Application of environmentally friendly and fire-safe transformer liquids
Submitting Institution
University of ManchesterUnit of Assessment
Electrical and Electronic Engineering, Metallurgy and MaterialsSummary Impact Type
TechnologicalResearch Subject Area(s)
Chemical Sciences: Inorganic Chemistry, Physical Chemistry (incl. Structural)
Engineering: Materials Engineering
Summary of the impact
    Research on ester liquids (ELs) has proved they can be used in
      high-voltage (HV) transformers,
      bringing economic and safety advantages to the power industry and
      environmental benefits to
      society. Impact includes revisions to National Grid's oil policy
      recommending ester-filled HV
      transformers for use in London and the design and operation of the first
      132kV "green" transformer
      (valued between £1m and £2m). The research has led directly to the
      creation of two international
      standards for professionals in global power utilities specifying the use
      of ELs in transformers.
      These developments have contributed directly to Manchester SME M&I
      Materials increasing sales
      from £15m (2008) to £29m (2012).
    Underpinning research
    The impact arises from research undertaken in Manchester from 2004 to
      date, with major
      publications from 2007 onwards. The key researchers were:
    
      - Professor Zhongdong Wang (Lecturer 2000-2007, SL 2007-2009, Professor
        2009-date)
 
      - Dr Qiang Liu (PDRA 2011-2012, Lecturer 2012-date).
        PhD students included Dr Dan Martin (2004-2008), Dr Imad Khan
        (2005-2009), Dr Jie Dai (2005-2009),
        Dr Xin Wang (2008-2011) and Dr Xiao Yi (2008-2012).
 
    
    The aim of the research was to develop the electrical design criteria for
      ester-filled transformers;
      formulate an efficient method for impregnating the winding structure with
      ester liquids; and to
      understand the fault-diagnostic techniques required to design, manufacture
      and operate ester-filled
      HV transformers (HV refers to ≥ 132kV). Ester liquids have advantages over
      mineral oils in that
      they are biodegradable, both within soil and water, and they have a high
      flash-point, which makes
      them inherently safer, allowing a higher operating temperature.
    The key research findings are as follows:
    
      - AC breakdown voltages of ester liquids under homogeneous fields were
        proved to be similar to
        those of mineral oil [1].
 
      - Key electrical characteristics, such as partial discharge inception,
        propagation and discharge
        patterns, under extreme inhomogeneous AC fields were determined and
        recommendations made
        for new and amended IEC standards related to electrical testing of
        insulating liquids [5].
 
      - The breakdown voltage-gap distance equations for ester liquids were
        formulated. This involved
        the measurement of breakdown and pre-breakdown phenomena under standard
        lightning
        impulses, and established fast streamer-led breakdown theory as the main
        cause of failure for
        long liquid gaps [2] and complex insulation geometries involving
        pressboard (solid insulation
        barriers used in transformers) [6].
 
      - Empirical equations were developed that linked liquid viscosity,
        temperature and vacuum level
        with the processing time required for ester liquids to impregnate solid
        insulating materials [4].
 
      - Dissolved gas analysis for condition assessment was demonstrated to be
        appropriate for ester-filled
        transformers, although the gas amounts and types were modified [3].
 
    
    References to the research
    The research was published in the three most prestigious journals in the
      field of transformers and
      electrical insulation: IEEE Transactions on Dielectrics and
      Electrical Insulation, IET Electric Power
        Applications and IEEE Electrical Insulation Magazine. Paper
      [2] was cited by Dr Jan Hajek, Global
      Manager Basic Technology Development of ABB in his keynote address at the
      IEEE International
        Conference on Dielectric Liquids, Trondheim, 2011, as one of the two
      key liquid research
      breakthroughs in recent years.
    Key Publications
    
[2] Q. Liu and Z.D. Wang, "Streamer Characteristic and Breakdown in
      Synthetic and Natural Ester
      Transformer Liquids under Standard Lightning Impulse Voltage", IEEE
        Transactions on
        Dielectrics and Electrical Insulation, 2011, Vol.18, No.1, pp.
      285-294 (Scopus citations = 18).
      DoI 10.1109/TDEI.2011.5704520
     
Other Publications
    
[4] J. Dai and Z.D. Wang, "A Comparison of the Impregnation of Cellulose
      Insulation by Ester and
      Mineral Oil", IEEE Transactions on Dielectrics and Electrical
        Insulation, Vol.15, No.2, pp.374-381,
      April 2008. (Scopus citations = 8) DoI 10.1109/TDEI.2008.4483455
     
[5] Z.D. Wang, Q. Liu, X. Wang, P. Jarman and G. Wilson, "Discussion on
      Possible Additions to
      IEC 60897 and IEC 61294 for Insulating Liquid Tests". IET Electric
        Power Applications 2011;
      5(6): 486-493 (Scopus citations = 6). DoI 10.1049/iet-epa.2010.0209
     
[6] Q. Liu and Z.D. Wang, "Streamer Characteristic and Breakdown in
      Synthetic and Natural Ester
      Transformer Liquids with Pressboard Interface under Lightning Impulse
      Voltage", IEEE
        Transactions on Dielectrics and Electrical Insulation, 2011, Vol.18,
      No.6, pp. 1908-1917
      (Scopus citations = 4). DoI 10.1109/TDEI.2011.6118629
     
Details of the impact
    Context
    Fire and potential subsequent explosion is the major risk factor when
      operating high-voltage
      transformers in dense urban environments. Power transformers require
      insulating and cooling
      media, most commonly mineral oil an environmentally hazardous material
      which is also a fire risk.
      Ester liquids mitigate these hazards and risks, since they are
      biodegradable and their flash point is
      350 °C versus 150 °C for mineral oil. Ester liquids have been used in low
      voltage (LV) transformers
      (≤33 kV) for twenty years, but were not used in HV transformers before
      2008. The Manchester
      research established the performance of ester liquids under all the
      critical stresses of HV
      applications, which enabled the manufacture and operation of HV
      ester-filled transformers with
      environmental performance and fire-safety level expected by society.
    Pathways to Impact
    
      - The research team worked directly with sponsoring companies — M&I
        Materials, Alstom Grid,
        UK Power Networks (UKPN), National Grid, Scottish Power, Electricity
        Northwest and TJH2B
        (2005 to date).
 
      - Technical papers were presented at leading international conferences
        in the field — IEEE:
        Conference on Electrical Insulation and Dielectric Phenomena (CEIDP),
        International
        Conference on Solid Dielectrics (ICSD), International Conference on
        Dielectric Liquids· (ICDL)
        and International Symposium on High Voltage Engineering (ISH).
 
      - Presentations were regularly given to the Council on Large Electric
        Systems, (CIGRE)
        Session/Colloquium and working groups. CIGRE is the international
        association that develops
        professional practice guidance for engineers in the power system sector,
        and is the relevant
        technical council for the International Electrotechnical Commission
        (IEC).
 
    
    All these activities increased the awareness of HV performance of ester
      liquids by the industry.
    Reach and Significance of the Impact
    1. Changes to international standards and professional practice.
      International standards in the
      electrical industry are established by the IEC. The research [5]
      highlighted the need for updates to
      existing IEC standards for the use of ester oils in HV transformers; these
      are currently being
      implemented by IEC Committee TC10 [a]. These standards are supported by
      professional practice
      guidance through CIGRE technical brochures which are the main practice
      guides for power
      engineers internationally. The results from the Manchester research are
      the basis of several
      sections in "Experiences in Service with Insulating Liquids" (2010) [f]
      and "DGA in Non-Mineral Oils
      and Load Tap Changers and Improved DGA Diagnosis Criteria" (2010) [g].
    2. Ester liquid manufacturers: The research has enabled companies
      producing ester oils to
      expand their market from the small LV transformers that typically hold
      <100 litres to larger HV
      transformers that typically hold 40,000-80,000 litres of oil creating a
      5.5m litre annual global market
      [h]. In the UK M&I materials, a high growth SME, and a sponsor of the
      research at Manchester, is
      using the research results to support sales of Midel 7131. Their Technical
      Manager stated "in doing
      this, customers and potential customers are persuaded of the advantages of
      using these
      alternative fluids... M&I Materials' total sales increased from £15m
      in 2008 to £29m in 2012" [a].
    3. Transformer manufacturers: The equations developed in [4] and
      [6] enabled manufacturers to
      design and manufacture ester-filled transformers. In 2008 Alstom Grid, the
      third largest transformer
      manufacturer in the world, became the first manufacturer in the UK to
      design and manufacture an
      ester liquid-filled 132kV/33kV/90MVA transformer. Such transformers are
      large capital items
      (typically valued at £1-2m) that are only manufactured to order and this
      first transformer was
      installed in EDF Energy's network (see 4 below). Alstom Grid can now
      manufacture a sustainable
      range of green "eco-efficient" power transformers (10 to 200 MVA and up to
      245kV) [e], and
      continue to use the Manchester research to help design a 400kV
      ester-filled transformer insulation
      model to validate this technology for the highest UK transmission voltages
      [b].
    4. Distribution Utilities: Based on the statistical evidence in
      research output [1], EDF Energy
      (now UK Power Networks, the distribution utility for London) made a
      strategic decision to become
      the first utility to own and operate a "green" 132kV transformer using
      natural ester oils from
      renewable resources that are biodegradable and more fire resistant [d].
    5. Transmission Utilities: National Grid, the UK power
      transmission system operator, has used
      the Manchester research to revise their oil policy to enable the use of
      ester oils to meet fire-safety
      concerns. National Grid has also ordered the first fire-safe 400kV
      transformer prototype with
      20,000 litres of M&I Material Midel 7131, the liquid analysed at
      Manchester. The cost of each
      transformer is £1m-£2m [c].
    The improved fire safety and environmental benefits of ester oils are
      driving change internationally
      and we are aware of anecdotal reports of US based utilities changing the
      oil type in existing
      transformers in high risk locations such as Disneyland.
    Sources to corroborate the impact 
    a. Letter from Technical Manager, M&I Materials (CIGRE SC A2 WG A2.34
      convenor) —
      demonstrating the impact of the research on the company's sales and the
      impact on
      international best practice.
    b. Letter from Unit Managing Director, ALSTOM Grid Research &
      Technology Centre, Alstom
      Grid — supporting the technological impact on new products of manufacturer
      based in the
      UK
    c. Letter from Technical Lead on Transformers, National Grid (IEC
      transformer chair) —
      confirming the safety impact of ester liquids on the UK transmission
      operator.
    d. EDF Energy (now UKPN) on "green transformers" in 2008 — press release
      supporting the
      Manchester R&D involvement in the installation of the 1st
      green transformer.
    e. Alstom Green Power Transformer Brochure — product brochure describing
      the range of
      "green" transformers incorporating ester oils.
    f. "Experiences in Service with Insulating Liquids" (2010) — CIGRE
      brochure defining best
      practice using Manchester research results
    g. "DGA in Non-Mineral Oils and Load Tap Changers and Improved DGA
      Diagnosis Criteria"
      (2010) — CIGRE brochure defining best practice using Manchester research
      results
    h. Transforming the Transformer Industry, inform August 2008 — a paper
      informing the size of
      global market for ester liquids